Search results for "Urea glass route"
showing 4 items of 4 documents
Role of the thermal treatment on the microstructure of YAGG nanopowders prepared by urea glass route
2023
Yttrium aluminium gallium garnet (YAGG, Y3Al2Ga3O12) doped with rare-earth ions has drawn large attention owing to its optical properties with applications ranging from persistent luminescent phosphors to nanothermometers. Herein, three different YAGG materials were synthesized via the urea glass route followed by thermal treatment, relatively undoped; doped with Ce3+, Cr3+, and Nd3+; and doped with Ce3+, Cr3+, and Yb3+. The garnet formation was studied in situ upon thermal treatment from 300 to 1000 ◦C using synchrotron powder diffraction. Our results show that with this method, the onset of formation of the garnet is about 860 ◦C, with comparable cell parameters for both undoped and doped…
Influence of cerium content and heat treatment on Ce:YAG@glass wool nanostructures
2019
The paper reports the influence of cerium content and heat treatment on composition, structural features and optical properties of nanostructures constituted by a layer of Ce:YAG nanoparticles on glass wool (Ce:YAG@GW). The Ce:YAG@GW nanostructures were obtained embedding the glass wool (GW) in a gel-like precursor and calcining at 800 and 900 °C. Gel-like precursor of urea glass route (UGR) method has been used to prepare both nanostructures and Ce:YAG nanoparticles prepared as references. Structural properties were investigated by using X-ray diffraction (XRD) and infrared spectroscopy (IR). Results showed that the composition of the final products strongly depends both on the cerium cont…
Urea Glass Route as a Way to Optimize YAGG:Ce3+,Cr3+,Pr3+ Nanocrystals for Persistent Luminescence Applications
2022
A new approach for the synthesis of Y3Al2Ga3O12 (YAGG) nanophosphors allowing the preparation of crystallites with sizes starting from 45 nm is presented. The controllability of the energy and trap density of the resulting material samples by annealing temperature was confirmed by thermoluminescence (TL) measurements. It has been shown that the annealing of samples at temperatures up to 1300 degrees C does not cause any substantial growth of crystallites, still remaining below 100 nm, but leads to changes in the activation energy of the persistent luminescence (PersL) process. On the other hand, annealing above 1400 degrees C results in grain growth on the submicron scale, which was confirm…
Multimetallic Oxynitrides Nanoparticles for a New Generation of Photocatalysts
2019
A versatile synthetic strategy for the preparation of multimetallic oxynitrides has been designed and here exemplarily discussed considering the preparation of nanoscaled zinc-gallium oxynitrides and zinc-gallium-indium oxynitrides, two important photocatalysts of new generation, which proved to be active in key energy related processes from pollutant decomposition to overall water splitting. The synthesis presented here allows the preparation of small nanoparticles (less than 20 nm in average diameter), well-defined in size and shape, yet highly crystalline and with the highest surface area reported so far (up to 80 m2 g-1 ). X-ray diffraction studies show that the final material is not a…